Formal syntheses of (+/-)-pinnaic acid and (+/-)-halichlorine |
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| Authors: | Andrade Rodrigo B Martin Stephen F |
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| Institution: | Department of Chemistry and Biochemistry, The University of Texas, Austin, Texas 78712, USA. |
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| Abstract: | chemical reaction: see text]. Concise formal syntheses of marine alkaloids (+/-)-pinnaic acid (1) and (+/-)-halichlorine (2) have been accomplished from a common intermediate. The syntheses illustrate the utility of selective olefin cross metathesis methodologies for the elaboration of advanced synthetic intermediates in complex molecule synthesis. |
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