Nickel-catalysed addition of organoboronates to 1,3-dienes |
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| Authors: | Shirakawa Eiji Takahashi Go Tsuchimoto Teruhisa Kawakami Yusuke |
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| Affiliation: | Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan. shira@jaist.ac.jp |
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| Abstract: | Aryl- and alkenylboronates were found to add to 1,3-dienes in the presence of a catalytic amount of bis(1,5-cyclooctadiene)nickel, where a proton source in combination with a solvent considerably controls the regioselectivity. |
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