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Abatement of oxalates catalyzed by Fe-silica structured surfaces via cyclic carboxylate intermediates in photo-Fenton reactions
Authors:Bozzi Anna  Yuranova Tatiana  Mielczarski J  Lopez A  Kiwi J
Affiliation:Laboratory of Photonics and Interfaces, Institute of Molecular Chemistry and Biology, Swiss Federal Institute of Technology, Lausanne 1015, Switzerland.
Abstract:Novel silica/Fe structured fabrics were observed to degrade oxalates only under light irradiation showing the formation and disappearance of Fe-carboxylates and the concomitant recycling of the resulting Fe-ions back to the structured catalyst surface.
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