Spontaneous assembly of a hydrogen-bonded tetrahedron |
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| Authors: | Field Jason E Combariza Marianny Y Vachet Richard W Venkataraman D |
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| Institution: | Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA. |
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| Abstract: | Triphenylamine ortho-tricarboxylic acid (1) has been synthesized and the crystal structure reported. This molecule is shown to spontaneously self-assemble into a hydrogen-bonded tetrahedron. Furthermore, Electrospray Ionization Mass Spectroscopy shows evidence for the stability of such aggregates from an ethanol/water solution. |
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