C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents |
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| Authors: | Merceron Nathalie Baceiredo Antoine Gornitzka Heinz Bertrand Guy |
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| Institution: | Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Université Paul Sabatier, 118, route de Narbonne, 31062 Toulouse, France. |
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| Abstract: | C-Phosphanyl-C-chloroiminium salts formally react as phosphonio(amino)carbenes with tert-butyl isocyanide and trimethylphosphine, and as R2NC+ with vinyl ether and diisopropylamine. |
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