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Mechanism of formation of short metal-ligand bonds in linear molecules CuCl2 and NiCl2 molecules |
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| Authors: | Yu. V. Rakitin V. T. Kalinnikov S. G. Khodasevich V. M. Novotortsev |
| Affiliation: | (1) Tananaev Institute of Rare Elements and Mineral Chemistry and Technology, Kola Research Center, Russian Academy of Sciences, ul. Fersmana 14, Apatity, Murmansk oblast, 184200, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
| Abstract: | The electronic structures of the CuCl2 and NiCl2 linear molecules were analyzed in the framework of the extended version of the angular overlap model. The anomalously short metal-ligand bonds in these molecules were shown to be due to the strong sd-mixing of the orbitals of the metal ions. |
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