Rare-gas matrix shift calculations of CO Cameron bands |
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| Authors: | HH Mohammed AM Taleb J Fournier |
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| Institution: | Iragi Atomic Energy Commission, Tuwaitha, Iraq;Department of Physics, College of Science, Baghdad, Iraq;Departement de Physique, Université de Paris Sud (Centre d''Orsay), Orsay, France |
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| Abstract: | Using both dispersive and inductive interactions, calculations have been made to account for the matrix red-shifts of the Cameron band emissions of CO(a3 Π → X1Σ+) isolated in Nc, Ar and Kr matrices at 4.8 K. Our experimental results along with the matrix shift calculations led us to conclude that CO a3Π forms a bond with the rare-gas atoms whose strength was found to increase from Nc to Kr. |
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