In situ crystallization of low-melting ionic liquids |
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Authors: | Choudhury Angshuman R Winterton Neil Steiner Alexander Cooper Andrew I Johnson Kathleen A |
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Affiliation: | Liverpool Centre for Materials and Catalysis, Department of Chemistry, University of Liverpool, UK. |
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Abstract: | Single crystals of five very low-melting ionic liquids, [emim]BF4 (mp -1.3 degrees C), [bmim]PF6 (+1.9 degrees C), [bmim]OTf (+6.7 degrees C), [hexpy]NTf2 (-3.6 degrees C), and [bmpyr]NTf2 (-10.8 degrees C), have been grown using a combined calorimetric and zone-melting approach and their crystal structures determined by X-ray diffraction. |
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