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Mesoporous silica anchored Ru catalysts for highly enantioselective hydrogenation of beta-ketoesters
Authors:Kesanli Banu  Lin Wenbin
Affiliation:Department of Chemistry, University of North Carolina, Chapel Hill, 27599, USA.
Abstract:Recyclable and reusable mesoporous silica anchored Ru catalysts based on 4,4'-substituted BINAPs were synthesized and used for the hydrogenation of beta-alkyl beta-ketoesters with up to 98.6% e.e. and beta-aryl beta-ketoesters with up to 95.2% e.e.
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