Mesoporous silica anchored Ru catalysts for highly enantioselective hydrogenation of beta-ketoesters |
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Authors: | Kesanli Banu Lin Wenbin |
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Affiliation: | Department of Chemistry, University of North Carolina, Chapel Hill, 27599, USA. |
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Abstract: | Recyclable and reusable mesoporous silica anchored Ru catalysts based on 4,4'-substituted BINAPs were synthesized and used for the hydrogenation of beta-alkyl beta-ketoesters with up to 98.6% e.e. and beta-aryl beta-ketoesters with up to 95.2% e.e. |
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