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热电材料的热输运调控及其在微型器件中的应用
引用本文:宋君强, 史迅, 张文清, 陈立东. 热电材料的热输运调控及其在微型器件中的应用[J]. 物理, 2013, 42(02): 112-123. DOI: 10.7693/wl20130204
作者姓名:宋君强  史迅  张文清  陈立东
作者单位:1.中国科学院上海硅酸盐研究所 高性能陶瓷和超微结构国家重点实验室 上海 200050
摘    要:热电能量转换技术是一种利用材料实现热能和电能直接相互转换的清洁能源技术。热电材料的性能是决定热电转换效率的关键因素,而热电材料的性能优化涉及电输运和热输运性能的协同优化。文章介绍了近期热电材料中热输运的调控机制和方法,其中重点论述了基于原子分子层次调控热传导的宽频声子散射效应和横波阻尼效应,以及低维结构和复合材料中的基于纳米微米尺度的微结构调控。最后介绍了室温附近热传导的调控机制及其在高效微型热电器件研发中的应用和进展。

关 键 词:热电能量转换技术  热电材料  热导率  声子散射  微型热电器件
收稿时间:2012-11-01

Heat conduction in thermoelectric materials and micro-devices
SONG Jun-Qiang, SHI Xun, ZHANG Wen-Qing, CHEN Li-Dong. Heat conduction in thermoelectric materials and micro-devices[J]. PHYSICS, 2013, 42(02): 112-123. DOI: 10.7693/wl20130204
Authors:SONG Jun-Qiang  SHI Xun  ZHANG Wen-Qing  CHEN Li-Dong
Affiliation:1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure,Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 200050,China
Abstract:Thermoelectric energy conversion technology is a clean-energy technology, which can convert energy directly between heat and electricity using thermoelectric materials. The conversion efficiency is mainly determined by the performance of the material, which includes the electrical and thermal transport properties. Asuitable balance between the latter must be found to optimize the thermoelectric properties. This paper describes recent developments in minimizing the heat conduction in thermoelectric materials and micro-devices, focussing on the effect of wide-spectrum phonon scattering and the damping of phonon transverse waves in semiconductor compounds, and phonon scattering by the interfaces and defects in low-dimension structures and thermoelectric composites. Finally, an overview of recent advances in high performance thermoelectric micro-devices improved by the suppression of heat conduction around room temperature will be given.
Keywords:thermoelectric energy conversion technology  thermoelectric materials  thermal conductivity  phonon scattering  thermoelectric micro-devices
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