169Tm NMR study of the high-Tc superconductor TmBa2Cu3O6.92

The ground state of Tm³⁺ ion (4t²,³H₆) in a crystal electric field (CEF) of TmBaCuO is a singlet, separated from the lowest excited states by an energy gap of 100÷130 cm^?1. The pulsed NMR of¹⁶⁹Tm nuclei (spinI=1/2) in a magnetically-oriented TmBa₂Cu₃O_6.92 power is studied at temperatures 1.5÷4.2 K. Two sorts of Tm nuclei are observed: rapidly relaxing Tm1 (≥80% of total amount, having relaxation timesT ₁ ⁽¹⁾ ≈35 ms,T ₂ ⁽¹⁾ =80÷250 μs) and slowly relaxing Tm2 nuclei (≦20%,T ₁ ⁽²⁾ =300÷1000 μs). The¹⁶⁹Tm NMR spectra are described by the spin-Hamiltonian ?₁ = ??Σγ _i H _i I _i (i = x,y,z), where |γ _x ⁽¹⁾/2π| = 5.3(1), |γ _y ⁽¹⁾/2π| = 6.6(1), |γ _x ⁽²⁾/2π| = |γ _y ⁽²⁾/2π| = 5.1(1), |γ _z ⁽¹⁾/2π| = |γ _z ⁽²⁾/2π| = 2.3(1) kHz/Oe, and axesx, y, z coincide with the crystal axesa, b, c. The Tm1 and Tm2 nuclei are identified as those belonging to orthorhombic (CEF of D_2h symmetry) and tetragonal (D_4h) phases of the TmBaCuO compound, respectively. Two-exponential and nearly temperature-independent nuclear relaxation is observed at temperatures 1.5÷4.2 K. The smallestT ₂ ⁽¹⁾ -values (≈80 μs) found for the orthorhombic (superconducting) phase in an external field H perpendicular to the crystalc-axis agree fairly well with those one could expect due to the dipole-dipole interaction of thulium nuclei. However, the slowing down of this rapid relaxation of the nuclear transverse magnetization in a field H‖c as well as the origin of unusually largeT ₂ ⁽²⁾ -values remain unclear.