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铀在有机合成中的应用研究进展
引用本文:陈思禹,于吉攀,梅雷,赵玉宝,柴之芳,石伟群.铀在有机合成中的应用研究进展[J].中国科学:化学,2021(1).
作者姓名:陈思禹  于吉攀  梅雷  赵玉宝  柴之芳  石伟群
作者单位:南华大学化学化工学院;中国科学院高能物理研究所;中国科学院宁波材料技术与工程研究所
基金项目:科学挑战计划(编号:TZ2016004);国家自然科学基金(编号:21806167,21925603);中国科学院青年创新促进会基金(编号:2017020)资助项目。
摘    要:铀储量丰富,是人类未来可持续发展的重要资源.随着人们对铀独特电子结构及其性质的深入认识,铀的资源化及其潜在应用也获得科学家的广泛关注.本文总结了近年来铀在有机合成中的最新研究成果,并对未来发展趋势进行了展望.该综述主要内容包括四价铀和六价铀催化的有机转化研究.

关 键 词:  有机合成  光催化  路易斯酸催化

Research progress on application of uranium in organic synthesis
Siyu Chen,Jipan Yu,Lei Mei,Yubao Zhao,Zhifang Chai,Weiqun Shi.Research progress on application of uranium in organic synthesis[J].Scientia Sinica Chimica,2021(1).
Authors:Siyu Chen  Jipan Yu  Lei Mei  Yubao Zhao  Zhifang Chai  Weiqun Shi
Institution:(School of Chemistry and Chemical Engineering,University of South China,Hengyang 421000,China;Laboratory of Nuclear Energy Chemistry,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing 100049,China;Engineering Laboratory of Advanced Energy Materials,Ningbo Institute of Materials Technology&Engineering,Chinese Academy of Sciences,Ningbo 315201,China)
Abstract:Uranium,as an important resource for the sustainable development of mankind in the future,is plentiful in reserves.With the deep understanding of the unique electronic structure and properties of uranium,the resourcing and potential applications of uranium have gained extensive attention.This review summarized the application of uranium in organic synthesis and its development tendency,which mainly includes the organic conversion catalyzed by uranium(valence+4 and+6).
Keywords:uranium  organic synthesis  photocatalysis  Lewis acid catalysis
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