Improving current and mitigating energy loss in ternary organic photovoltaics enabled by two well-compatible small molecule acceptors |
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Authors: | Sun Yanna Gao Huan-Huan Wu Simin Meng Lingxian Wan Xiangjian Li Mengyang Ma Zaifei Guo Ziqi Li Shitong Zhang Hongtao Li Chenxi Chen Yongsheng |
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Institution: | 1.State Key Laboratory and Institute of Elemento-Organic Chemistry, The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, Institute of Polymer Chemistry, Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, China ;2.Center for Advanced Low-dimension Materials, Stage Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China ; |
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Abstract: | Ternary organic photovoltaic(OPV) strategy is an effective but facile approach to enhance the photovoltaic performance for single-junction devices. Herein, a series of ternary OPVs were fabricated by employing a wide bandgap donor(PBDB-TF) and two acceptor-donor-acceptor(A-D-A)-type nonfullerene small molecule acceptors(NF-SMAs, called F-2 Cl and 3 TT-OCIC). As the third component, the near-infrared SMA, 3 TT-OCIC, has complementary absorption spectrum, narrow bandgap and wellcompatible crystallization property to the host acceptor(F-2 Cl) for efficient ternary OPVs. With these, the optimal ternary devices yield significantly enhanced power conversion efficiency of 15.23%, one of the very few examples with PCE higher than15% other than Y6 systems. This is mainly attributed to the increased short-circuit current density of 24.92 m A cm-2 and dramatically decreased energy loss of 0.53 e V. This work presents a successful example for simultaneously improving current,minimizing energy loss and together with modifying the morphology of active layers in OPVs, which will contribute to the further construction of high performance ternary OPVs. |
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