Complex [MoO2(L)(CH3OH)] (L2- = 3-methoxysalicylidenemonoethanolimine anion): Synthesis,crystal and molecular structures |
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| Authors: | V S Sergienko V L Abramenko Yu N Mikhailov M D Surazhskaya |
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| Institution: | 1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
2. Dal’ East Ukrainian National University, Molodezhnyi kvartal 20a, Lugansk, 91034, Ukraine
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| Abstract: | The complex MoO2(L)(CH3OH)] (where L2- is 3-methoxysalicylidenemonoethanolimine anion) has been prepared and structurally characterized by X-ray diffraction. The molybdenum atom has an octahedral coordination to two ligands in cis-positions to each other, two oxygen atoms, the nitrogen atom of the tridentate bis(chelate) L2- ligand, and also the oxygen atom of methanol. Strong O-H?O hydrogen bonds (O?O, 2.598 Å) link pairs of molecules into centrosymmetric pseudo-dimers. |
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