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On equilibria with participation of gold(I) complexes in sulfite-thiocarbamide media |
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| Authors: | I V Mironov D B Kal’nyi V V Kokovkin |
| Institution: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia 2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia |
| Abstract: | The constants of protonation and sulfite ligand substitution by thiocarbamide for Au(SO3) 2 3? complex were determined. Mixed forms Autu(SO3)? and probably binuclear complex Au2tu2SO3] were shown to occur in noticeable concentrations in sulfite-thiocarbamide media in addition to Autu 2 + and Au(SO3) 2 3? complex forms. |
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