New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes |
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Authors: | Page Philip C Bulman Farah Mohamed M Buckley Benjamin R Blacker A John |
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Affiliation: | Department of Chemistry, Loughborough University, Loughborough, Leicestershire LE11 3TU, England. p.c.b.page@lboro.ac.uk |
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Abstract: | A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%. |
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