| Na_3Fe（C_2O_4）_3·5H_2O的合成、晶体结构及谱学表征 |
| |
| 引用本文： | 郑瑜,朱自莹.Na_3Fe（C_2O_4）_3·5H_2O的合成、晶体结构及谱学表征[J].结构化学,1994,13(3):216-220. |
| |
| 作者姓名： | 郑瑜 朱自莹 |
| |
| 作者单位： | 福建物质结构研究所，上海有机化学研究所 |
| |
| 摘 要： | 合成并测定三价铁乙二酸配合物Ｎａ_３Ｆｅ（Ｃ_２Ｏ_４）_３．５Ｈ_２Ｏ的单晶结构。晶体属单斜晶系，空间群为Ｃ２／ｃ，晶胞参数ａ＝１７．３８０（１），ｂ＝１２．６９３（５），ｃ＝１５．１９６（６），β＝１００．４７（６）°，Ｖ＝３２９７（３），Ｚ＝８，Ｄ_ｃ＝１．７４ｇ／ｃｍ￣（－３）．Ｍ_ｒ＝４７８．９８，μ＝１０．５１ｃｍ￣（－１）。结构的偏离因子Ｒ＝０．０３６，Ｒ_ｗ＝０．０５６。此外，还测定了化合物的红外、拉曼、紫外一可见吸收光谱、穆斯堡尔谱及磁化率等。并通这有关信息讨论了该化合物的结构。
|
| 关 键 词： | 铁乙二酸配合物，合成，结构，谱学表征 |
Crystal Structure and Spectroscopies of the Complex[Na_3Fe (C_2O_4 )_3]·5H_2O |
| |
| Zheng Yu,Wu Qiang-Jin,Xie Wei-Wen,Zhang Lin-Na.Crystal Structure and Spectroscopies of the Complex[Na_3Fe (C_2O_4 )_3]·5H_2O[J].Chinese Journal of Structural Chemistry,1994,13(3):216-220. |
| |
| Authors: | Zheng Yu Wu Qiang-Jin Xie Wei-Wen Zhang Lin-Na |
| |
| Abstract: | Title complex was synthesized,and its structure has been determined by X-ray single crystal diffraction analysis.C_6H_(10)O_(17)FeNa_3,M_r= 478.98,crystallizes in monoclinic space group C2/c with a=17.380(1),b=12.693(5),c=15.196(6),β=100.47(6)°,V=3297(3),Z=8,D_c=1.74 g/cm-3,μ=10.51 cm-1.F(000)=1736.The final R=0.036,R_w=0.056.The characterization of the complex by IR,Raman,UV-Vis,Mossbauer spectra and magnetic susceptibility are reported,and their relevance to structure has been discussed as well. |
| |
| Keywords: | Iron trisoxalato complex crystal structure spectroseopic characterization |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
