| 1—间甲氧苯基—2—二甲胺甲基环己醇的合成与结构研究 |
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| 引用本文： | 乔本志 晋春. 1—间甲氧苯基—2—二甲胺甲基环己醇的合成与结构研究[J]. 高等学校化学学报, 1997, 18(6): 902-905 |
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| 作者姓名： | 乔本志 晋春 |
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| 作者单位： | 太原工业大学应用化学系!太原，030024 |
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| 摘 要： | 通过间溴苯甲醚与２－二甲胺甲基环己酮反应制得１－间甲氧苯基－２－二胺甲基环己醇，对其分离得到相应的顺反异构体，对反应的立体化学进行了分析，并对＾１３Ｃ ＮＭＲ谱确定了顺反异构体的构型。
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| 关 键 词： | 间甲氧苯基 二甲胺甲基 环己醇 合成 顺反异构体 |
Synthesis and Structure of 1-(m-Methoxyphenyl)-2-(dimethylaminomethyl) cyclohexanol |
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| QIAO Ben-Zhi, JIN Chun, SUN Wen-Yang. Synthesis and Structure of 1-(m-Methoxyphenyl)-2-(dimethylaminomethyl) cyclohexanol[J]. Chemical Research In Chinese Universities, 1997, 18(6): 902-905 |
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| Authors: | QIAO Ben-Zhi JIN Chun SUN Wen-Yang |
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| Abstract: | The reaction of 2-(dimethylaminomethyl) cyclohexanone with m-anisyl magne-sium bromlde yielded the title compound as a mixture of Z- and E-isomers, which were sepa-rated into their pure component by fractional crystallization. Their configurations were de-termined by 13C NMR spectra. The stereochemistry of the reaction was discussed. |
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| Keywords: | 1-(m-Methoxyphenyl)-2-(dimethylaminomethyl)-cyclohexanol Synthesis Separation Structure |
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