Heterolytic activation of H-X (X = H, Si, B, and C) bonds: an experimental and theoretical investigation |
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Authors: | Nagaraja C M Parameswaran Pattiyil Jemmis Eluvathingal D Jagirdar Balaji R |
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Institution: | Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore, India. |
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Abstract: | The highly electrophilic, coordinatively unsaturated, 16-electron Ru(P(OH)3)(dppe)2]OTf]2 (dppe = Ph2PCH2CH2PPh2) complex 1 activates the H-H, the Si-H, and the B-H bonds, in H2(g), EtMe2SiH and Et3SiH, and H3B.L (L = PMe3, PPh3), respectively, in a heterolytic fashion. The heterolysis of H2 involves an eta2-H2 complex (observable at low temperatures), whereas the computations indicate that those of the Si-H and the B-H bonds proceed through unobserved eta1-species. The common ruthenium-containing product in these reactions is trans-Ru(H)(P(OH)3)(dppe)2]OTf], 2. The Ru(P(OH)3)(dppe)2]OTf]2 complex is unique with regard to activating the H-H, the Si-H, and the B-H bonds in a heterolytic manner. These reactions and the heterolytic activation of the C-H bond in methane by the model complex Ru(POH)3)(H2PCH2CH2PH2)2]Cl]OTf], 4, have been investigated using computational methods as well, at the B3LYP/LANL2DZ level. While the model complex activates the H-H, the Si-H, and the B-H bonds in H2, SiH4, and H3B.L (L = PMe3, PPh3), respectively, with a low barrier, activation of the C-H bond in CH4 involves a transition state of 57.5 kcal/mol high in energy. The inability of the ruthenium complex to activate CH4 is due to the undue stretching of the C-H bond needed at the transition state, in comparison to the other substrates. |
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