| 二氯-二[2-甲氧基-6-(2'-羟乙基亚胺基甲基)苯酚]合镉(II)的 结构再研究 |
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| 引用本文： | 崔学桂,胡清萍,胡盛志.二氯-二[2-甲氧基-6-(2'-羟乙基亚胺基甲基)苯酚]合镉(II)的 结构再研究[J].化学学报,2000,58(3):356-357. |
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| 作者姓名： | 崔学桂 胡清萍 胡盛志 |
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| 作者单位： | [1]山东大学化学学院,济南 [2]厦门大学化学系,厦门 |
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| 基金项目： | 山东省自然科学基金(Y96B10029)和山东大学晶体材料国家重点实验室资助课题 |
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| 摘 要： | 标题化合物的晶体结构曾用单斜晶系的空间群Cc描述。我们再研究确定其空间群应为正交晶系的Fdd2。修正涉及晶体的晶系、晶类和布拉维格子类型的改变,但仍属可呈现非线性光学活性的非心对称空间群。给出了在空间群Fdd2时的非氢原子坐标和主要键长和键角值。
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| 关 键 词： | 苯酚P 镉络合物 甲氧基 亚胺P 晶体结构 空间群 |
| 修稿时间： | 1999年7月2日 |
A reinvestigation of the structure of bischlorine-bis[2-methoxyl-6- (2'-hydroxyethyl imidogen methyl) phenol] cadmium(II) complex |
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| CUI Xue - Gui HU Qing - Ping.A reinvestigation of the structure of bischlorine-bis[2-methoxyl-6- (2'-hydroxyethyl imidogen methyl) phenol] cadmium(II) complex[J].Acta Chimica Sinica,2000,58(3):356-357. |
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| Authors: | CUI Xue - Gui HU Qing - Ping |
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| Institution: | Shandong Univ., College of Chem.Jinan(250100);Xiamen Univ, Dept Chem. Xiamen(361005) |
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| Abstract: | The crystal structure of the title complex previously described as monoclinic, space group Cc is corrected to be orthorhombic, space group Fdd2 with cell parameters a = 1,1661 (2)nm, b - 3.0956(10)nm, c = 1.5475(3)nm, V=5.586(2)nm3, Z = 8. Corrections involve changing its crystal system and class as well as the lattice type, but the structure still belongs to one of the non - centrosymmetric space groups, which is necessary for the potential non - linear optical materials. Average atomic coordinates and selected bond lengths and angles are given. |
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| Keywords: | cadimium complex space - group corrections |
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