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X-ray absorption studies of the structure of nanocrystalline oxides
Affiliation:1. Normandie Université, INSA Rouen, UNIROUEN, CNRS, CORIA, 76000 Rouen, France;2. Institut de Radioprotection et de Sureté Nucléaire (IRSN), PSN-RES, SCA, LPMA, Gif-sur-Yvette 91192, France;3. Institut de Physique de Rennes, Université de Rennes I, 35042 Rennes, France;4. Institute for Technical Chemistry, Karlsruhe Institute of Technology, 76021 Karlsruhe, Germany;5. Environnement SA, 78304 Poissy, France;6. Laboratoire de Physico-Chimie des Matériaux et Catalyse, Université de Bejaia, 06000 Bejaia, Algeria;7. Synchrotron SOLEIL, L''orme des Merisiers Saint-Aubin – BP 48, Gif-sur-Yvette 91192, France
Abstract:
X-ray absorption spectroscopy is a prime tool in probing the local structure in condensed matter. This contribution describes some of the applications of this technique to probe the microstructure of nanocrystalline oxides. By the use of specific examples four areas will be covered, namely the effect of grain size and preparation route on microstructure, the locating of dopant sites and the chemical nature of metal/oxide catalysts. The materials involved are tin oxide, lithium niobate, titanium dioxide and copper/ceria.
Keywords:
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