A new class of chiral tetrahydropyran-4-one catalyst for asymmetric epoxidation of alkenes |
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| Affiliation: | 1. Department of Chemistry, Northeastern University, 360 Huntington Avenue, Boston, MA 02115, United States;2. Division of Nuclear Medicine and Molecular Imaging, Massachusetts General Hospital, Department of Radiology, Harvard Medical School, 55 Fruit St., White 427, Boston, MA 02114, United States;3. German Cancer Consortium (DKTK), Heidelberg, Germany;4. Department of Nuclear Medicine, University Hospital Freiburg, Hugestetterstrasse 55, D-79106 Freiburg, Germany;5. German Cancer Research Center (DKFZ), Heidelberg, Germany;1. Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India;2. Department of Spectroscopy, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India;1. University of Cukurova, Vocational School of Ceyhan, Adana, Turkey;2. University of Cukurova, Faculty of Sciences and Letters, Department of Chemistry, Adana 01330, Turkey;3. University of Cukurova, Faculty of Pharmacy, Department of Biochemistry, Adana 01330, Turkey;4. University of Cukurova, Vocational School of Imamoglu, Adana, Turkey;1. Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China;2. State Key Laboratory of NBC Protection for Civilian, Beijing 102205, PR China |
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| Abstract: | A new class of chiral α-oxygenated-tetrahydropyran-4-ones for asymmetric epoxidation of alkenes using Oxone® is described, affording epoxides with up to 83% ee. |
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