Local structure analysis of YSZ by Y-89 MAS-NMR |
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| Institution: | 1. State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi''an Jiaotong University, Xi''an, Shaanxi Province 710049, PR China;2. Xi''an Thermal Power Research Institute Co., Ltd, Xi''an, Shannxi, PR China;3. Joining and Welding Research Institute, Osaka University, Osaka, Ibaraki, Japan;1. State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi''an Jiaotong University, Xi''an, Shaanxi 710049, China;2. Zhenhuo Plasma Technology Company, Chengdu, Sichuan 610065, China |
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| Abstract: | The local coordination structure around Yttrium ions in yttria stabilized zirconia (YSZ) has been investigated by 89Y MAS-NMR. The NMR spectrum showed multiple peaks corresponding to yttrium ions in different coordination numbers. The compositional dependence of spectra was observed. Yttrium ions of different oxygen coordination number were quantified. The oxygen vacancy concentration around the cations was determined. It was found that the vacancies were distributed around Zirconium ions in lower Y2O3 concentrations, and the vacancy concentration located to Yttrium began increasing at concentrations above 10 mol% Y2O3. The local structure change was able to be directly observed by 89Y NMR measurements. |
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