Stepwise formation of "organometallic boxes" with half-sandwich Ir, Rh and Ru fragments |
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| Authors: | Han Ying-Feng Lin Yue-Jian Weng Lin-Hong Berke Heinz Jin Guo-Xin |
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| Affiliation: | Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China. |
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| Abstract: | Octanuclear complexes with half-sandwich Ir, Rh and Ru fragments and tetra(4-pyridyl)porphyrin (L1) and oxalate (L2) spacer ligands [(Cp*M)4L1]2[L2]4 (M = Ir (6a) M = Rh (6b)), [((cymene)Ru)4(L1)]2[L2]4 were prepared and characterized. |
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