Analysis of the Coriolis-coupled band system of ν5, ν2, and 2ν3 of methyl-d3 iodide |
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Authors: | Hiroatsu Matsuura Takehiko Shimanouchi |
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Abstract: | The Coriolis-coupled band system of ν5, ν2, and 2ν3 of CD3I was analyzed by making use of all of the experimental data now available. These data included the high-resolution infrared spectra, microwave spectra, and laser Stark spectra. The analysis gave values, more precise than before, of the spectroscopic constants for ν5, ν2, and 2ν3 and the interaction constants. The determination of the rotational constant A for 2ν3 gave a value for , with which all of the αA constants for CD3I have been completed. These αA values were incorporated with the known value of A6 to give a value for A0. |
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