Highly efficient hydrazination of conjugated nitroalkenes via imidazole or DMAP mediated Morita-Baylis-Hillman reaction |
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Authors: | Dadwal Mamta Mobin Shaikh M Namboothiri Irishi N N |
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Institution: | Department of Chemistry, Indian Institute of Technology, Bombay, Mumbai. |
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Abstract: | Novel alpha-hydrazino-alpha,beta-unsaturated nitroalkenes, which exhibit dynamic phenomenon on the NMR time scale, were synthesized in excellent yields via imidazole or DMAP mediated Morita-Baylis-Hillman (MBH) type reaction of nitroalkenes with azodicarboxylates. |
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