Solvothermal Synthesis,Crystal Structure and Properties of the First Organic‐templated Holmium Sulfate [C2N2H10]3[Ho2(SO4)6·2H2O] |
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| Authors: | Wanli Zhou Qi Chen Dunru Zhu Yan Xu Prof Dr |
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| Institution: | 1. College of Chemistry and Chemical Engineering, State Key Laboratory of Materials‐oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China;2. Department of Chemistry, Tonghua Normal University, Tonghua 134002, P. R. China;3. Institute of Functionalized Chemistry Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian Liaoning, 116029, P.R. China |
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| Abstract: | The first organic amine‐templated holmium sulfate C2N2H10]3Ho2(SO4)6·2H2O] ( 1 ) has been synthesized solvothermally and has been structurally characterized by single‐crystal X‐ray diffraction studies, IR spectroscopic, thermogravimetric (TG) and inductivity coupled plasma (ICP) measurements. Crystal analyses of compound 1 showed a novel inorganic layer constructed from the zigzag and helical –Ho–O–S–O–]n chains, both of the chains are connected by μ‐2 SO42– groups to form 10‐membered rings. The solvent plays an important role during the formation of 1 . |
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| Keywords: | Solvothermal synthesis Template synthesis Organometallic compounds Holmium sulfate Lanthanides |
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