[Gd(OH)(H2O)(b18c6)]I(I3)(CH3CN), a New Cationic In‐cavity Complex with Iodide and Triiodide as Anions |
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| Authors: | Christine Walbaum Ingo Pantenburg Gerd Meyer Prof. Dr. |
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| Affiliation: | Universit?t zu K?ln–Department für Chemie, Institut für Anorganische Chemie, Greinstra?e 6, 50939 K?ln, Germany |
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| Abstract: | Single crystals of [Gd(OH)(H2O)(b18c6)]I(I3)(CH3CN) were obtained from an acetonitrile solution of GdI3, I2 and benzo‐18‐crown‐6. The crystal structure (monoclinic, P21/a (no. 14), Z = 4, a = 1233.8(1) pm, b = 1925.0(2) pm, c = 1252.3(1) pm, β = 104.375(7)°) contains hydroxide bridged cationic dimers and iodide as well as triiodide as anions. |
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| Keywords: | Gadolinium Crown complexes Crystal structure Iodine Polyiodides |
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