Synthesis of Chloro Boryl Complexes by Oxidative Addition of B–Cl Bonds |
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| Authors: | Holger Braunschweig Prof Dr Marco Fuß Krzysztof Radacki Katharina Uttinger |
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| Institution: | Institut für Anorganische Chemie, Julius Maximilians Universit?t Würzburg, Am Hubland, 97074 Würzburg, Germany |
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| Abstract: | Some platinum boryl complexes of the type trans‐(Cy3P)2Pt(Cl){B(Cl)R}] ( 1 : R = NMe2, 2 : R = Mes, 3 : R = tBu) were synthesized by oxidative addition of the corresponding dichloroboranes to Pt(PCy3)2]. All the compounds were characterized by multinuclear NMR spectroscopy in solution. Furthermore, a single crystal analysis was acquired from 2 , that confirms the strong trans‐influence of this boryl ligand. |
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| Keywords: | Boryl complexes Oxidative addition Chloroboranes Platinum |
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