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Synthesis,Structure and Characterization of Dinuclear Pentacoordinate Molybdenum(V) Complexes with Thiosemicarbazone Ligands |
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| Authors: | Vi?nja Vrdoljak Prof Dalibor Mili? Marina Cindri? Dubravka Matkovi?‐?alogovi? Jana Pisk Marina Markovi? Predrag Novak |
| Institution: | Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia |
| Abstract: | New dinuclear pentacoordinate molybdenum(V) complexes, Mo2VO3L2] L = thiosemicarbazonato ligand: C6H4(O)CH:NN:C(S)NHR′ and C10H6(O)CH:NN:C(S)NHR′; R′ = H, CH3, C6H5) were obtained either by oxygen atom abstraction from MoVIO2L with triphenylphosphine or by using Mo2O3(acac)4] in the reaction with the corresponding ligands H2L. Crystal and molecular structure of Mo2O3{C6H4(O)CH:NN:C(S)NHC6H5}2] · CH3CN has been determined by the single‐crystal X‐ray diffraction method. |
| Keywords: | Molybdenum Thiosemicarbazones Coordination chemistry Dinuclear complexes Oxo‐bridged complexes |