Synthesis and Characterization of an Inorganic‐Organic Hybrid Layered Zinc Phosphite [(C2H3N3)Zn(HPO3)] |
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| Authors: | Xianchun Liu Yan Xing Dr Li Liu Shuyan Song Gaijuan Li Ning Xu |
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| Institution: | College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China |
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| Abstract: | A inorganic‐organic hybrid zinc phosphite (C2H3N3)Zn(HPO3) ( 1 ) has been prepared under solvothermal conditions in the presence of 1,2,4‐triazole (trz) ligand.Its structure was determined by single‐crystal X‐ray diffraction, and further characterized by powder X‐ray diffraction (XRD), FTIR spectroscopy, elemental analysis, ICP analysis, thermogravimetric analysis and fluorescent spectrum. It crystallizes in the monoclinic system, space group P21/n, a = 7.5515(6) Å, b = 9.1813(8) Å, c = 10.0125(8) Å, β = 111.267(1)°, V = 646.92(9) Å3, Z = 4. The structure consists of left‐handed and right‐handed helical chains that are connected through bridging oxygen atoms to form a two‐dimensional layer structure with 4.8‐net. The compound exhibits intense photoluminescence upon photo‐excitation at 326 nm. |
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| Keywords: | Zinc Solvothermal synthesis Helical chains Zinc phosphites Crystal structure |
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