Synthesis and Crystal Structure of KSc(HPO4)2 |
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| Authors: | Prashanth W Menezes Stefan Hoffmann Yurii Prots Rüdiger Kniep Prof Dr |
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| Institution: | Max‐Planck‐Institut für Chemische Physik fester Stoffe, N?thnitzer Strasse 40, 01187 Dresden, Germany |
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| Abstract: | KSc(HPO4)2 was obtained by hydrothermal synthesis. The crystal structure was determined from single‐crystal X‐ray data: orthorhombic, space group Pnma (No. 62), a = 14.5095(10), b = 5.4260(4), c = 8.4882(5) Å, V = 668.26(8) Å3 and Z = 4. The crystal structure of KSc(HPO4)2 represents a new structure type containing twelve‐ and four‐membered rings forming channels along 010] built of alternating ScO6 octahedra and HPO42? groups. Potassium ions reside within the twelve membered ring channels. |
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| Keywords: | Scandium Potassium Phosphate Channels |
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