A New Main Group Metal Coordination Polymer: Synthesis,Structure, and Dielectric Constant Property of [Na(C6H4N5)(H2O)2]n |
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| Authors: | Da‐Wei Fu Dr Jia‐Zhen Ge Yi Zhang Heng‐Yun Ye |
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| Institution: | Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P. R. China |
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| Abstract: | The reaction of NaOH with 4‐(2H‐tetrazol‐5‐yl)pyridine affords the first tetrazole‐pyridine sodium coordination polymer with chain structure, Na(C6H4N5)(H2O)2]n ( 1 ). The compound could be characterized by single‐crystal X‐ray diffraction analysis. The temperature dependence of dielectric permittivity remains unchanged almost within the measured temperature range of 80 K to 270 K at 1 <SC>MH</SC>z, and the frequency dependence of the permittivity showed rapidly drops from 31.5 to 4.3 within the measured frequency range of 200 to 1 MHz at room temperature. |
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| Keywords: | Nitrogen heterocycles Structure elucidation Dielectric constant Sodium X‐ray diffraction |
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