Ag9I(GeO4)2 – Containing Two‐dimensionally Linked [IAg12] Metallo Complexes |
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Authors: | Dragan Pitzschke Jan Curda Martin Jansen Prof Dr |
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Institution: | Max‐Planck‐Institut für Festk?rperforschung, Heisenbergstr. 1, 70569 Stuttgart, Germany |
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Abstract: | Ag9I(GeO4)2 was obtained for the first time by reacting a stoichiometric mixture of Ag2O, AgI, and GeO2, at elevated oxygen pressures, adding a small portion of distilled water. The synthesis was done at 480 °C and 110 MPa of oxygen pressure. It crystallizes in space group C2/m, with the unit cell dimensions a = 17.3736(9) Å, b = 6.9177(4) Å, c = 5.7176(3) Å, β = 105.501(3)°, V = 662.18(6) Å3, and Z = 2. The structure refinement was based on 638 independent reflections and resulted in R1 = 6.26 %. The crystal structure consists of isolated (GeO4)4– ions and IAg12] metallo complexes, the latter are interconnected through each two common edges and corners corresponding to IAg6/1Ag6/2], thus forming infinite layers within the (100) plane. The Ag/I slabs are stacked perpendicular to the a‐axis with an interlayer distance of about 3.4 Å. The (GeO4)4– anions are located in the gaps between the silver iodide layers. According to the results of impedance measurements, Ag9I(GeO4)2 is a good silver ion conductor. The compound shows an increase in the ionic conductivity in the temperature range of 30 to 310 °C, and has a silver ion conductivity of 1.1 × 10–3 Ω–1 cm–1 at room temp. The activation energy for silver ion conduction is 0.35 eV, in the temperature range from 25 to 190 °C. |
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Keywords: | Silver Iodine Germanate Ionic conductivity Crystal structure |
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