Nucleophilic Substitution Reactions of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine. 3. Reaction of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine with Azides and Hydrazine |
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| Authors: | A V Shastin T I Godovikova B L Korsunskii |
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| Institution: | (1) Russian Academy of Sciences, Institute of Problems of Chemical Physics, Chernogolovka, 142432 Moscow Region, Russia;(2) N. D. Zelinsky Institute of Organic Chemistry, Moscow, 117913, Russia |
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| Abstract: | As a result of nucleophilic substitution of the trinitromethyl groups in 2,4,6-tris(trinitromethyl)-1,3,5-triazine, the corresponding monoazido and diazido derivatives have been synthesized. The reaction of the starting triazine with hydrazine acetate in the presence of trifluoroacetic acid leads to 1-acetyl-2,2-bis4,6-bis(trinitromethyl)-1,3,5-triazin-2-yl]hydrazine. |
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| Keywords: | sodium azide hydrazine trimethylsilyl azide 2 4 6-tris(trinitromethyl)-1 3 5-triazine nucleophilic substitution |
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