| 新试剂氟磺酸9,10—二甲基吖啶发光性能及其测定金的研究 |
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| 引用本文： | 庄惠生,张帆.新试剂氟磺酸9,10—二甲基吖啶发光性能及其测定金的研究[J].分析试验室,1993,12(4):46-51. |
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| 作者姓名： | 庄惠生 张帆 |
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| 作者单位： | 福州大学化学系，福州大学化学系，福州大学化学系 福州 350002，福州 350002，福州 350002 |
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| 摘 要： |
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| 关 键 词： | 化学发光 金 氟磺酸 二甲基吖啶 |
Study on the Determination of Gold with a New Reagent 9, 10-Dimethyl Acridinium Fluorosulfonate and Its Luminescent Property |
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| Zhuang Huisheng,Zhang Fan and Liao Yong.Study on the Determination of Gold with a New Reagent 9, 10-Dimethyl Acridinium Fluorosulfonate and Its Luminescent Property[J].Chinese Journal of Analysis Laboratory,1993,12(4):46-51. |
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| Authors: | Zhuang Huisheng Zhang Fan and Liao Yong |
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| Abstract: | The Luminescent properties of a new reagent 9,10-dimethyl acridinium fluorosulfonate (DMAF) and the reaction mechanism of a new chemiluminescent system DMAF-KOH-H_2O-AuCl_3 were studied, and a new chemiluminescent method for the determination of trace gold was established. The method is simple, selective and highly sensitive, the detection limit is 0.3ng/mL Au, the linear range is from 0.5ng/mL to 800ng/mL Au, the relative standard deviation is 5.0% and 6.2% for 200ng/mL and 10ng/mL Au, respectively. The system is particularly stable,a long standing time of eight hours for a standard solution of AuCI_4~- did not essentially affect is chemiluminescent reaction. |
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| Keywords: | Chemiluminescence fluorescence gold determination 9 10-dimethyl acridinium fluorosulfonate |
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