Comparison of 13C- and 1H-Magnetic Resonance Spectroscopy as Techniques for the Quantitative Investigation of Dynamic Processes. The cope rearrangement in bullvalene |
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| Authors: | Jean F M Oth Klaus Müllen Jean-Marie Gilles Gerhard Schrder |
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| Institution: | Jean F. M. Oth,Klaus Müllen,Jean-Marie Gilles,Gerhard Schröder |
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| Abstract: | The potential advantages of 13C-(1H-noise decoupled) spectroscopy (in the Fourier transform mode) over 1H-spectroscopy for the quantitative investigation of molecular dynamic process is discussed. The Cope rearrangement in bullvalene, an example of complex exchange of spins over different magnetic sites, has been studied by both kinds of spectroscopy as a test. |
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