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Cyclometalated rhodium(III) complex with phen-dione ligand |
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| Authors: | Ghobad Mansouri Hassan Hadadzadeh Hamid Reza Khavasi |
| Affiliation: | a Department of Chemistry, University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran b Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran c Department of Chemistry, Shahid Beheshti University, P.O. Box 19395, Tehran, Iran |
| Abstract: | The novel cyclometalated Rh(III) complex, [Rh(phpy-κ2N,C2′)2(phen-dione)]PF6, where phpy-κ2N,C2′ is pyridine-2-yl-2-phenyl and phen-dione is 1,10-phenanthroline-5,6-dione has been prepared and characterized by elemental analysis, IR, 1H NMR, and electronic absorption spectroscopies, cyclic voltammetry, and X-ray crystallography. The crystal structure of [Rh(phpy-κ2N,C2′)2(phen-dione)]PF6·CH3CN shows that the coordination geometry around the Rh(III) is a distorted octahedron, with bite angles of 76.13°-81.09° for all three bidentate ligands. |
| Keywords: | Rh(III) complex Cyclometalated complex 1,10-Phenanthroline-5,6-dione 2-Phenylpyridine Crystal structure Cyclic voltammetry |
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