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Synthesis, molecular, crystal and electronic structure of [(C6H6)RuCl(1,10-C12H8N2)]Cl |
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| Authors: | JG Ma?ecki M Jaworska |
| Institution: | a Department of Inorganic and Radiation Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland b Department of Theoretical Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland c Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, ?ód? University of Technology, 116 ?eromski St., 90-924 ?ód?, Poland |
| Abstract: | The (C6H6)RuCl(1,10-C12H8N2)]Cl complex has been prepared and studied by IR, UV-Vis, 1H NMR spectroscopy and X-ray crystallography. The complex was prepared in reaction of (C6H6)RuCl2]2 with 1,10-phenatroline in acetone. The electronic spectrum of the compound has been calculated using the TDDFT method. |
| Keywords: | Ruthenium arene complexes Phenanthroline X-ray structure Bond valence TDDFT method |
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