Synthesis and characterization of bimetallic ruthenium complexes connected through linear (CH)14 chain |
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Authors: | Ping Yuan Guang-ao Yu Sheng Hua Liu |
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Affiliation: | a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China |
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Abstract: | Treatment of RuHCl(CO)(PPh3)3 with (3E,5E,7E,9E,11E)-HCC-(CHCH)5- CCH produces [RuCl(CO)(PPh3)2]2[μ-(CHCH)7]. The later complex reacts with PMe3 to give [RuCl(CO)(PMe3)3]2[μ-(CHCH)7], the structure of which has been confirmed by X-ray diffraction. The through-space distance from one Ru to the other is 19.88 Å. |
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Keywords: | Bimetallic ruthenium complex Polyenediyl bridge Synthesis Electrochemistry |
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