Chiral, bridged bis(imidazolin-2-ylidene) complexes of palladium |
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| Authors: | Sabine K Schneider |
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| Institution: | Department Chemie, Lehrstuhl für Anorganische Chemie, Technische Universität München, Lichtenbergstraße 4, D-85747 Garching, Germany |
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| Abstract: | Varieties of chiral, bridged bisimidazolium salts as well as the synthesis of palladium complexes of general formula  with the corresponding chelating N-heterocyclic carbene ligands is reported. This is the first systematic study of chiral bis(imidazolin-2-ylidene)palladium(II) complexes bearing chiral groups on the endocyclic nitrogens. Structural proof of such a chiral palladium(II) complex is presented by way of an X-ray diffraction study of complex 3a. |
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| Keywords: | Chelating ligands Chiral ligands Bisimidazolium salts Palladium |
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