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Reactions of cyclopentadienes with phorone
Authors:N. B. Ivchenko  P. V. Ivchenko  I. E. Nifant'ev  I. A. Kashulin  I. V. Taidakov  L. G. Kuz'mina
Affiliation:(1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation;(2) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907 Moscow, Russian Federation
Abstract:Reactions of different cyclopentadienes with phorone were studied. Nonsubstituted and monosubstituted cyclopentadienes form annelation products,viz., 4,4,8,8-tetramethyl-1, 3a,4,5,6,7,8,8a-octahydroazulen-6-ones. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 721–724, April, 2000.
Keywords:cyclopentadienes  intermolecular cyclization  Michael addition  azulenones
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