Preferential solvation of dithizone in chloroform in cyclohexane |
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| Authors: | Saswati P. Bag Henry Freiser |
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| Affiliation: | Department of Chemistry, University of Arizona, Tucson, AZ 85721 U.S.A. |
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| Abstract: | The molar absorptivity of diphenylthiocarbazone in cyclohexane is dramatically enhanced by the addition of small quantities of chloroform. This has been attributed to the formation of a 1:2 dithizone chloroform complex (formation constant 104.0) rather than simple nonspecific solvent effects. |
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