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Potentiometric titration of hydroxide,aluminate and carbonate in sodium aluminate solutions
Authors:Z. Kowalski  W. Kubiak  A. Kowalska
Affiliation:Institute of Materials Science, Academy of Mining and Metallurgy, al. Mickiewicza 30, KrakówPoland;Regional Laboratory of Physicochemical Analysis and Structural Research, Jagellonian University, KrakówPoland
Abstract:An automated potentiometric titration of hydroxide, aluminate and carbonate in sodium aluminate solutions is described. The addition of barium chloride before titration with hydrochloric acid enables the three components to be determined in one run, involving neutralization of hydroxide, protonation of aluminate and dissolution of barium carbonate. The accuracy and precision of the method are satisfactory for a rapid method used for control of aluminum oxide production.
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