Amperometric detection of amines and amino acids in flow injection systems with a nickel oxide electrode |
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Authors: | Ben S Hui CO Huber |
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Institution: | Department of Chemistry, University of Wisconsin-Milwaukee, Milwaukee, WI 53201 U.S.A. |
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Abstract: | The use and characteristics of a nickel oxide electrode as a detector for amines in a flow injection system are described. The anodic electrode reaction mechanism involves a higher oxidation state of nickel maintained by the applied potential (+0.49 V vs. SCE). The electroanalytical parameters are investigated and the currents for a series of amines and amino acids are compared. Two electrode configurations are compared. The flow injection technique is shown to be suitable for buffered 25-μl samples of pH as low as 3. The linear range for glycine is 10-6–10-3 M with detection limits of a few nanograms. |
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