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A concise stereoselective formal total synthesis of the cytotoxic macrolide (+)-Neopeltolide via Prins cyclization |
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| Authors: | Jhillu Singh Yadav Gunda Gopala Krishana Satya Narayana Kumar |
| Affiliation: | Division of Organic Chemistry-I, Indian Institute of Chemical Technology, Hyderabad-500007, India |
| Abstract: | A convergent and highly stereoselective formal total synthesis of the naturally occurring, cytotoxic 14-membered macrolide neopeltolide has been achieved via two Prins cyclizations. |
| Keywords: | Prins cyclization Ozonolysis Esterification Macrolide |
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