Novel class of non-ionic monocatenary and bolaform alkylglycoside surfactants. Synthesis by microwave-assisted glycosylation and olefin cross-metathesis or by ‘click-chemistry’: physicochemical studies |
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Authors: | Virginie Neto |
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Affiliation: | Laboratoire de Chimie des Substances Naturelles (L.C.S.N.), Université de Limoges, Faculté des Sciences et Techniques, 123 Avenue Albert Thomas, 87060 Limoges Cedex, France |
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Abstract: | We develop herein the synthesis of a new class of monocatenary and bolaform surfactants from d-glucose, d-galactose and lactose. Two main pathways have been investigated: microwave-assisted glycosylation followed by olefin cross-metathesis, and the one-step click-chemistry methodology. Tensioactive properties of these new compounds have been studied in order to characterize the physicochemical behaviour of these new carbohydrate-based compounds in water. |
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Keywords: | Surfactants Alkylglycosides Carbohydrate Microwave Cross-metathesis CuAAC click-chemistry |
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