Convenient method for the synthesis of C-phosphorylated N-arylformamidines |
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Authors: | Anatoliy Marchenko |
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Affiliation: | Institute of Organic Chemistry National Academy of Sciences of Ukraine, Murmanska 5, Kyiv-94, 02094, Ukraine |
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Abstract: | C-Phosphorylated (PV) arylformamidines have been prepared by the reaction of N-arylamidotrichloromethyl derivatives of phosphorus, thiophosphorus, and selenophosphorus acids with secondary amines. Dependence of the reaction on the nature of chalcogene, electronic and steric factors has been studied. By reduction of N-arylformamidinophosphonoselenides the corresponding C-phosphorylated (PIII) arylformamidines have been synthesized. |
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Keywords: | C-Phosphorylated arylformamidines N-arylamidotrichloromethylphosphine Trichloromethylphosphonates Gem-dichlorophosphaaziridine |
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