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Iron/copper promoted oxidative homo-coupling reaction of terminal alkynes using air as the oxidant
Authors:Xu Meng
Affiliation:State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Tianshui Road, Lanzhou 730000, PR China
Abstract:An inexpensive catalytic system, which used a readily available Fe(acac)3 and trace quantity of Cu(acac)2 as the co-catalyst and air as the oxidant for the homo-coupling of terminal alkynes, has been developed. The catalytic system could also apply to the cross-coupling reaction of two different terminal alkynes.
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