Enhancing the solubility for hypervalent ortho-sulfonyl iodine compounds |
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| Authors: | Bindu V Meprathu |
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| Institution: | Department of Chemistry, Case Western Reserve University, Cleveland, OH 44106, United States |
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| Abstract: | The synthesis and characterization of new hypervalent iodine reagents ArINTs (2a), ArIO (3a), and ArIO2 (4a) (Ar=2-tert-butylsulfonyl-5-tert-butylphenyl) are described. These reagents are compared to previously reported analogous set of reagents Ar=2-tert-butylsulfonylphenyl and found to have significantly enhanced solubility and similar chemical reactivity. The X-ray crystal structures of 4a and of ArI (1a) (Ar=2-tert-butylsulfonyl-5-tert-butylphenyl) are discussed and compared. These reagents find use in atom and group transfer reactions. |
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| Keywords: | Polyvalent organoiodine compounds Iodyl benzene Iodoxybenzene Iodosylbezene |
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